Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Allyl Alcohol → 1-Allyloxyethoxyethane
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Allyl Alcohol | HCID 7858 | — |
| 반응물 | Ethyl vinyl ether | HCID 8023 | — |
| 반응물 | Bicyclo[2.2.1]heptane-1-methanesulfonic acid, 7,7-dimethyl-2-oxo-, (1S)- | HCID 18462 | — |
| 생성물 | 1-Allyloxyethoxyethane | HCID 12739596 | — |
반응 단계
Allyl alcohol (46.8 ml. 40 g., 0.69 mol) and ethyl vinyl ether (98.8 ml., 74.5 g., 1.033 mols) were stirred together at -12°. dl-Camphorsulfonic acid (150 mg.) was added acid and stirring continued for 3 hours at that temperature. The mixture was then washed 1×100 ml. saturated NaHCO3, 1×100 ml. brine, dried and stripped to yield title product as an oil (100 ml., essentially quantitative yield). 1H-nmr: 1.14 (t, 3H), 1.29 (d, 3H), 3.56 (dp, 2H), 4.06 (m, 2H), 4.75 (q, 1H), 5.26 (m, 2H), 5.99 (m, 1H).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04762921 |
| 출처 데이터셋 | uspto-grants-1988_08 |
| ORD ID | ord-b9c46c681b884c24ae14b41e12d792e2 |
| 출처 메모 | uspto-grants-1988_08 |