Sulfur Dioxide → Magnesium sulfite

HRID 349140

반응식

HRID 349140 반응식
[S:1](=[O:3])=[O:2].[Mg:4].[OH-:5].[OH-].[Mg+2]>>[S:1]([O-:5])([O-:3])=[O:2].[Mg+2:4].[S:1](=[O:5])([OH:3])[O-:2].[Mg+2:4].[S:1](=[O:5])([OH:3])[O-:2]

참가 물질

5

반응물 3

HCID 1119Sulfur Dioxide2회HCID 73981Magnesium Hydroxide2회HCID 5462224Magnesium

생성물 2

HCID 3014583Magnesium sulfiteHCID 10130272Magnesium bisulfite

실험 절차

In lieu of a limestone or lime-based scrubbing system, flue gas containing sulfur dioxide may be treated by passing it through a scrubbing unit that utilizes a magnesium-containing scrubbing agent, e.g., a magnesium hydroxide slurry. The magnesium hydroxide reacts with sulfur dioxide to produce magnesium sulfite and magnesium bisulfite. The magnesium hydroxide slurry also reacts with hydrochloric acid in the flue gas, producing magnesium chloride, although there is very little hydrochloric acid in the flue gas compared to sulfur dioxide. The following chemical reactions occur in the scrubbing unit: SO2+Mg(OH)2→MgSO3+H2O  (1) H2O+SO2+MgSO3→Mg(HSO3)2  (2) Mg(HSO3)2+Mg(OH)2→2MgSO3  (3) 2HCl+Mg(OH)2→MgCl2→2H2O  (4)

후처리

  1. additionmay be treated
  2. additioncontaining

출처 및 근거

ORD 기록
ord-5d444098fac94d62b14b1dbb5e096d5c
출처 데이터셋
uspto-grants-2007_02
특허 번호
US07179438B2

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