3-(allylsulphinyl)-L-alanine → Allicin

HRID 349159

반응식

HRID 349159 반응식
N[C@H](C(O)=O)C[S:4]([CH2:6][CH:7]=[CH2:8])=[O:5]>O>[CH2:8]=[CH:7][CH2:6][S:4](=[O:5])[S:4][CH2:6][CH:7]=[CH2:8]

참가 물질

3

반응물 1

HCID 873103-(allylsulphinyl)-L-alanine

생성물 1

HCID 65036Allicin수율 21.8%

시약·촉매·용매 1

HCID 962Water용매

실험 절차

10 grams of L-Alliin was added to 200 ml of distilled water and 12 grams of fresh garlic cloves were added as described above in (Example 3). When the reaction was complete, after approximately 3 hrs., the reaction mixture was extracted with a suitable solvent such as 50 ml of diethyl ether. The ether layer was separated, dried over Magnesium Sulphate, filtered and evaporated to a straw coloured liquid yielding 1 gram of allicin. This was dissolved in distilled water (100 ml) and the 1% Allicin solution was stored at −20 C.

후처리

  1. additionwere added
  2. extraction, the reaction mixture was extracted with a suitable solvent such as 50 ml of diethyl ether
  3. customThe ether layer was separated
  4. dry with materialdried over Magnesium Sulphate
  5. filtrationfiltered
  6. customevaporated to a straw

출처 및 근거

ORD 기록
ord-a063c3bba0ce4218bf0360ec6a6a8742
출처 데이터셋
uspto-grants-2007_02
특허 번호
US07179632B2

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