Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Tributylstannane → {1-[4-(Benzyloxy)phenyl]ethenyl}(tributyl)stannane
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Tributylstannane | HCID 5948 | — |
| 반응물 | 4'-Benzyloxyphenyl acetylene | HCID 1490323 | — |
| 용매 | Tetrahydrofuran | HCID 8028 | — |
| 생성물 | {1-[4-(Benzyloxy)phenyl]ethenyl}(tributyl)stannane | HCID 18436367 | — |
반응 단계
1-benzyloxy-4-ethynyl-benzene (70 g, 0.3365 mol), Bu3SnH (59 mL, 0.3365 mol) and Ph(PP3)2Cl2 (120 mg, 0.1718 mmol) were stirred in THF (500 mL) at 25° C. for 16 h and then refluxed for 1 h. The resulting solution was concentrated and then purified on SiO2 (2% ˜5% ethyl acetate/hexane) to yield tributyl-[1-(4-benzyloxy-phenyl)-vinyl]-stannane.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US07183445B2 |
| 출처 데이터셋 | uspto-grants-2007_02 |
| ORD ID | ord-548b48d2ddeb4a00adf7671038cb8c9d |
| 출처 메모 | uspto-grants-2007_02 |