Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
5,7-dihydro-6H-dibenz[c,e]azepine-6carbonitrile → dodecyl 5,7-dihydro-6H-dibenz[c,e]azepine-6-thiocarboximidate
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 5,7-dihydro-6H-dibenz[c,e]azepine-6carbonitrile | HCID 19833886 | — |
| 반응물 | Sodium dodecane-1-thiolate | HCID 23672953 | — |
| 용매 | 1-Dodecanethiol | HCID 8195 | — |
| 생성물 | dodecyl 5,7-dihydro-6H-dibenz[c,e]azepine-6-thiocarboximidate | HCID 19833911 | — |
반응 단계
starting from 5,7-dihydro-6H-dibenz[c,e]azepine-6-carbonitrile and sodium dodecanethiolate in 1-dodecanethiol there is obtained dodecyl 5,7-dihydro-6H-dibenz[c,e]azepine-6-thiocarboximidate, which is purified by flash chromatography on silica gel using n-hexane/ethyl acetate (1:1) as the eluent; 1H-NMR(CDCl3): 0.88 (t, CH3), 1.2-2.0 (20H), 2.5 (t, SCH2), 4.43 (s, 4H), 7.3-7.7 (8H);
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04766115 |
| 출처 데이터셋 | uspto-grants-1988_08 |
| ORD ID | ord-c0e9a35f334147d79dbd084f56ef54e6 |
| 출처 메모 | uspto-grants-1988_08 |