Hexane → cis-Stilbene

HRID 351960

반응식

HRID 351960 반응식
[C:1]1([C:7]#[C:8][C:9]2[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.CCCCCC>C1COCC1>[C:1]1(/[CH:7]=[CH:8]\[C:9]2[CH:10]=[CH:11][CH:12]=[CH:13][CH:14]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1

참가 물질

4

반응물 2

HCID 8058HexaneHCID 10390Diphenylacetylene

생성물 1

HCID 5356785cis-Stilbene

시약·촉매·용매 1

HCID 8028Tetrahydrofuran용매

실험 절차

In the foregoing epititanations of diphenylacetylene conducted in THF or hexane, parallel epititanations were conducted in the same manner but the hydrolytic workup in each case was performed with 3N DCl in D2O. In these experiments the cis-stilbene isolated was >98% dideuteriated at the vinylic carbon atoms (12).

출처 및 근거

ORD 기록
ord-9507fa7fcc184888bfcbd3570c598bd7
출처 데이터셋
uspto-grants-2004_06
특허 번호
US06743872B1

연결된 노트

불러오는 중…