Furfural → 1-(2-Furyl)-1,4-butanediol

HRID 352129노트

반응식

HRID 352129 반응식
S1[CH:5]=[CH:4][C:3]([CH:6]([OH:11])[CH2:7][CH2:8][CH2:9][OH:10])=C1.[O:12]1C=CC=[C:13]1C=O>O1CCCC1>[O:12]1[CH:13]=[CH:5][CH:4]=[C:3]1[CH:6]([OH:11])[CH2:7][CH2:8][CH2:9][OH:10]

참가 물질

4

반응물 2

HCID 7362FurfuralHCID 227150901-(3-Thienyl)-1,4-butanediol

생성물 1

HCID 138155341-(2-Furyl)-1,4-butanediol

시약·촉매·용매 1

HCID 8028Tetrahydrofuran용매

실험 절차

The Grignard reagent prepared in Example 26 step (a) (0.7 M, 28 ml, 19.6 mmol), and furan-2-carboxaldehyde (1.92 g, 20 mmol) in anhydrous tetrahydrofuran (15 ml) were used to prepare the sub-title compound, using the procedure described in Example 26 step (a). The product was a colourless oil (2.69 g, 88%).

출처 및 근거

ORD 기록
ord-51b020c78196475d8b72e615693d5058
출처 데이터셋
uspto-grants-2004_06
특허 번호
US06743939B2

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