돌아가기
Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
HRID 353015생성일: 2026년 10월 26일

Triethylamine → p-(1-(Cyclohexylethoxy)ethoxy)styrene p-Hydroxystyrene

https://huagongshe.com/reaction/353015

반응식

참여 물질

역할이름HCID투입량
반응물TriethylamineHCID 8471—
반응물Ethyl AcetateHCID 8857—
반응물4-VinylphenolHCID 62453—
용매Propylene glycol methyl ether acetateHCID 7946—
생성물p-(1-(Cyclohexylethoxy)ethoxy)styrene p-HydroxystyreneHCID 86598586—

반응 조건

온도25 °C

반응 단계

p-Hydroxystyrene (VP-8000, produced by Nippon Soda Co., Ltd.) in an amount of 70 g was dissolved in 320 g of propylene glycol monomethyl ether acetate (PGMEA) with heating, dehydrated by vacuum distillation, and then cooled to 25° C. To this solution, 0.35 g of pyridinium p-toluenesulfonate and 22.4 g of cyclohexane ethanol were added, and further 17.5 g of t-butyl vinyl ether was added at a slow speed. In the resulting mixture, reaction was run for 5 hours at 20° C. Thereafter, the reaction solution was admixed with 0.28 g of triethylamine and 320 ml of ethyl acetate, and washed with 150 ml each of distilled water for three times. Therefrom, the solvent was distilled away, and the residue was concentrated. The thus obtained oil was dissolved in 100 ml of acetone, and poured slowly into 2 liter of distilled water. As a result, a powdery matter separated out. This powdery matter was filtered off and dried to yield 54 g of the desired resin.

출처 및 근거

DOI10.6084/m9.figshare.5104873.v1
특허 번호US06749987B2
출처 데이터셋uspto-grants-2004_06
ORD IDord-931071c8e5724b2eb9cdaa8a6a2eb9a0
출처 메모uspto-grants-2004_06