Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Furan → Phosphonic acid, 2-furanyl-, diethyl ester
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Furan | HCID 8029 | — |
| 반응물 | Diethyl chlorophosphate | HCID 13139 | — |
| 반응물 | Butyllithium | HCID 178418339 | — |
| 용매 | Diethyl Ether | HCID 3283 | — |
| 생성물 | Phosphonic acid, 2-furanyl-, diethyl ester | HCID 12485182 | — |
반응 단계
A solution of furan (1 mmole) in diethyl ether was treated with TMEDA (N,N,N′N′-tetramethylethylenediamine) (1 mmole) and nBuLi (2 mmole) at −78° C. for 0.5 h. Diethyl chlorophosphate (1.2 mmole) was added to the reaction mixture and stirred for another hour. Extraction and distillation gave diethyl 2-furanphosphonate as a clear oil.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US06756360B1 |
| 출처 데이터셋 | uspto-grants-2004_06 |
| ORD ID | ord-2cef6820965a4d6e82d57e609f00f9cd |
| 출처 메모 | uspto-grants-2004_06 |