Tributylvinyltin → HCID 18940943, 화합물

HRID 356038노트

반응식

HRID 356038 반응식
[C:1]([N:4]1[C:12]2[C:7](=[CH:8][C:9](I)=[C:10]([Cl:13])[CH:11]=2)[CH2:6][CH2:5]1)(=[O:3])[CH3:2].[CH:15]([Sn](CCCC)(CCCC)CCCC)=[CH2:16]>>[C:1]([N:4]1[C:12]2[C:7](=[CH:8][C:9]([CH:15]=[CH2:16])=[C:10]([Cl:13])[CH:11]=2)[CH2:6][CH2:5]1)(=[O:3])[CH3:2]

참가 물질

3

반응물 2

HCID 81998TributylvinyltinHCID 18940886HCID 18940886, 화합물

생성물 1

HCID 18940943HCID 18940943, 화합물

실험 절차

1-Acetyl-6-chloro-5-iodoindoline (D60) (0.19 g, 0.6 mmol) was treated with vinyl tributyltin as in the method developed by Stille (A. M. Echavarren and J. K. Stille, J. Am. Chem. Soc., 1987, 109, 5478) to give the title compound (0.13 g) as a brown oil which was used without further purification.

출처 및 근거

ORD 기록
ord-5244586881274912802ac99e6c10b71e
출처 데이터셋
uspto-grants-1998_11
특허 번호
US05834494

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