Oxalyl chloride → HCID 19612334, 화합물

HRID 356701노트

반응식

HRID 356701 반응식
[C:1]([O:5][O:6][C:7]([CH3:13])([CH3:12])[CH2:8][CH:9]([CH3:11])[OH:10])([CH3:4])([CH3:3])[CH3:2].[C:14](Cl)(=[O:18])[C:15]([Cl:17])=[O:16]>>[C:15]([Cl:17])(=[O:16])[C:14]([O:10][CH:9]([CH3:11])[CH2:8][C:7]([O:6][O:5][C:1]([CH3:4])([CH3:3])[CH3:2])([CH3:12])[CH3:13])=[O:18]

참가 물질

3

반응물 2

HCID 65578Oxalyl chloride2회HCID 220654633-t-Butylperoxy-1,3-dimethylbutanol

생성물 1

HCID 19612334HCID 19612334, 화합물수율 98.5%

실험 절차

In this example the product was prepared in two synthetic steps. In the first step 3-t-butylperoxy-1,3-dimethylbutanol was reacted with 100% molar excess of oxalyl chloride. Upon completion of the reaction the excess oxalyl chloride was stripped from the product at reduced pressure to produce 3-t-butylperoxy-1,3-dimethylbutyl chlorooxalate having an assay of 97.5% and in a corrected yield of 98.5%. In the second step 3-t-butylperoxy-1,3-dimethylbutyl chlorooxalate was reacted with 2,5-dimethyl-2,5-dihydroperoxyhexane, in the presence of pyridine, to yield the product as described below:

출처 및 근거

ORD 기록
ord-b2e0af4702314b298dcaeac2ef7eec95
출처 데이터셋
uspto-grants-1998_11
특허 번호
US05837782

반응 노트

불러오는 중…