Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Hydroxyamine hydrochloride → 1-Acetyl-1-(3,4-dichlorophenyl)cyclobutane oxime
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Hydroxyamine hydrochloride | HCID 443297 | — |
| 반응물 | 1-Acetyl-1-(3,4-dichlorophenyl)cyclobutane | HCID 13083139 | — |
| 반응물 | Sodium Acetate Trihydrate | HCID 23665404 | — |
| 용매 | Water | HCID 962 | — |
| 생성물 | 1-Acetyl-1-(3,4-dichlorophenyl)cyclobutane oxime | HCID 86031113 | — |
반응 단계
A mixture of 1-acetyl-1-(3,4-dichlorophenyl)cyclobutane (4.86 g) prepared as described in Example 1, hydroxylamine hydrochloride (1.6 g), sodium acetate trihydrate (3.3 g), industrial methylated spirit (15 ml) and water (2 ml) was heated under reflux for twenty hours. The cooled reaction mixture was poured into water and the oil which separated was cooled to give a solid which was recrystallised from industrial methylated spirit to give 1-acetyl-1-(3,4-dichlorophenyl)cyclobutane oxime (m.p. 120°-121° C.).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04767790 |
| 출처 데이터셋 | uspto-grants-1988_08 |
| ORD ID | ord-212ada1503ca49f38c304579d022218a |
| 출처 메모 | uspto-grants-1988_08 |