Water → HCID 54501552, 화합물

HRID 357156노트

반응식

HRID 357156 반응식
C(O[CH:4]=[C:5]1[S:9][C:8](=[O:10])[NH:7][C:6]1=[O:11])C.[Na].[CH2:13]([SH:15])[CH3:14].O>C(O)C>[CH2:13]([S:15][CH:4]=[C:5]1[S:9][C:8](=[O:10])[NH:7][C:6]1=[O:11])[CH3:14]

참가 물질

5

반응물 3

HCID 962WaterHCID 45051917Sodium ethanethiolHCID 537875085-(Ethoxymethylene)thiazolidine-2,4-dione

생성물 1

HCID 54501552HCID 54501552, 화합물

시약·촉매·용매 1

HCID 702Ethanol용매

실험 절차

To a suspension of 5.20 g of 5-(ethoxymethylene)thiazolidine-2,4-dione (1:1.71 mixture with thiazolidine-2,4-dione, about 13.9 mmol) in 50 ml of ethanol, 5.0 g (59 mmol) of ethanethiol sodium salt was added at room temperature, followed by stirring under heating conditions for 3 hours. After cooling, the reaction mixture was poured into water and adjusted to a pH level of about 2. The resulting precipitate was collected by filtration, washed with water and then with n-hexane/diethyl ether and dried to yield 1.38 g (52.0%, light yellow powder) of the desired product.

후처리

  1. additionwas added at room temperature
  2. temperatureAfter cooling
  3. filtrationThe resulting precipitate was collected by filtration
  4. washwashed with water
  5. dry with materialwith n-hexane/diethyl ether and dried

출처 및 근거

ORD 기록
ord-f2c262a790024d35b3922934d789170b
출처 데이터셋
uspto-grants-1998_11
특허 번호
US05840732

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