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Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
HRID 358382생성일: 2026년 10월 25일

2-Hydroxy-4-methoxybenzophenone → {4-Methoxy-2-[(prop-2-en-1-yl)oxy]phenyl}(phenyl)methanone

https://huagongshe.com/reaction/358382

반응식

참여 물질

역할이름HCID투입량
반응물2-Hydroxy-4-methoxybenzophenoneHCID 4632—
반응물Potassium IodideHCID 4875—
반응물Allyl chlorideHCID 7850—
반응물Potassium HydroxideHCID 14797—
용매TetrahydrofuranHCID 8028—
생성물{4-Methoxy-2-[(prop-2-en-1-yl)oxy]phenyl}(phenyl)methanoneHCID 14227056—

반응 단계

2-Hydroxy-4-methoxybenzophenone (114 parts) was dissolved in tetrahydrofuran (100 parts). Potassium hydroxide (30.9 parts) was added. By heating and stirring, complete dissolution was achieved. Allyl chloride (46.4 parts) and potassium iodide (4.2 parts) were added to this solution, which was then heated and refluxed for 8 hours. After cooling, it was washed with water and the solvent was removed by distillation. A crude product of the desired 2-allyloxy-4-methoxybenzophenone was obtained. It was recrystallized in n-hexane to obtain 125 parts of 2-allyloxy-4-methoxybenzophenone (melting point 40° C.) at 93% yield.

출처 및 근거

DOI10.6084/m9.figshare.5104873.v1
특허 번호US04467082
출처 데이터셋uspto-grants-1984_08
ORD IDord-b194dbbb179640d88942b8ef085f31a9
출처 메모uspto-grants-1984_08