4-Octylaniline → N-(p-octylphenyl)-2,4,6-triphenylpyridinium triflate

HRID 359305

반응식

HRID 359305 반응식
[O-:1][S:2]([C:5]([F:8])([F:7])[F:6])(=[O:4])=[O:3].[C:9]1([C:15]2[CH:20]=[C:19]([C:21]3[CH:26]=[CH:25][CH:24]=[CH:23][CH:22]=3)[CH:18]=[C:17]([C:27]3[CH:32]=[CH:31][CH:30]=[CH:29][CH:28]=3)[O+]=2)[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1.[CH2:33]([C:41]1[CH:47]=[CH:46][C:44]([NH2:45])=[CH:43][CH:42]=1)[CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][CH3:40]>C(O)C>[O-:4][S:2]([C:5]([F:8])([F:7])[F:6])(=[O:3])=[O:1].[CH2:33]([C:41]1[CH:42]=[CH:43][C:44]([N+:45]2[C:15]([C:9]3[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=3)=[CH:20][C:19]([C:21]3[CH:26]=[CH:25][CH:24]=[CH:23][CH:22]=3)=[CH:18][C:17]=2[C:27]2[CH:32]=[CH:31][CH:30]=[CH:29][CH:28]=2)=[CH:46][CH:47]=1)[CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][CH3:40]

참가 물질

4

반응물 2

HCID 853464-OctylanilineHCID 2778031AG-G-77560

생성물 1

HCID 20064818N-(p-octylphenyl)-2,4,6-triphenylpyridinium triflate

시약·촉매·용매 1

HCID 702Ethanol용매

실험 절차

A 4.58-g portion (0.01 mole) of 2,4,6-triphenylpyrylium triflate is added to 200 ml of ethanol. To this solution, 2.05 g (0.01 mole) of p-n-octylaniline is added. The mixture is refluxed for about 20 hours. Upon removing the ethanol by rotating evaporation, an orange oil remains. To remove the last of the ethanol the oil is placed under high vacuum.

후처리

  1. temperatureThe mixture is refluxed for about 20 hours
  2. customUpon removing the ethanol
  3. customevaporation
  4. customTo remove the last of the ethanol the oil

출처 및 근거

ORD 기록
ord-7852d11320734bafb0ba94ae0caa2fb1
출처 데이터셋
uspto-grants-1991_03
특허 번호
US05000873

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