Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Water → 3-[[3-(Hexadecyloxy)-2-methoxypropoxy]methyl]benzenemethanol
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Water | HCID 962 | — |
| 반응물 | 1-O-hexadecyl-2-O-methylglycerol | HCID 1380 | — |
| 반응물 | Sodium hydride | HCID 24758 | — |
| 반응물 | 1,3-Benzenedimethanol | HCID 69374 | — |
| 용매 | Dimethylformamide | HCID 6228 | — |
| 생성물 | 3-[[3-(Hexadecyloxy)-2-methoxypropoxy]methyl]benzenemethanol | HCID 19939554 | — |
반응 단계
To a suspension of 2.8 g of sodium hydride in 25 ml of dimethylformamide was added at 0° C. over 30 minutes a solution of 1,3-benzenedimethanol in 75 ml of dimethylformamide. After 30 minutes a solution of 3-(hexadecyloxy)-2methoxy-1-propanol, 4-methyl benzene sulfonate in 25 ml of dimethylformamide was added over 30 minutes. After stirring 18 hours the mixture was poured into water and extracted with ethylacetate. The solution was dried and the product was purified by chromatography giving 4.7 g.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05411983 |
| 출처 데이터셋 | uspto-grants-1995_05 |
| ORD ID | ord-b803c018fdff491c8fff6b3c2b716dd8 |
| 출처 메모 | uspto-grants-1995_05 |