Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Cetyl Alcohol → 8-(Hexadecyloxy)-7-methoxy-1-octene
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Cetyl Alcohol | HCID 2682 | — |
| 반응물 | Sodium hydride | HCID 24758 | — |
| 반응물 | p-Toluenesulfonate | HCID 85570 | — |
| 반응물 | 8-Hydroxy-7-methoxy-1-octene | HCID 19939570 | — |
| 용매 | Water | HCID 962 | — |
| 용매 | Dimethylformamide | HCID 6228 | — |
| 생성물 | 8-(Hexadecyloxy)-7-methoxy-1-octene | HCID 19939565 | — |
반응 단계
To a suspension of 7.4 g of 60% sodium hydride in 100 ml of dimethylformamide was added a solution of 8-hydroxy-7-methoxy-1-octene in 150 ml of dimethylformamide over 1.5 hours. A 63.4 g portion of the tosylate of 1-hexadecanol was added and the mixture was stirred for 18 hours, poured into water and extracted with ether. The ether solution was dried and evaporated. The residue was purified by chromatography giving 41.5 g of the title compound as a oil.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05411983 |
| 출처 데이터셋 | uspto-grants-1995_05 |
| ORD ID | ord-95f61b892d9b4419a2ca820c0f9db754 |
| 출처 메모 | uspto-grants-1995_05 |