Formic Acid → HCID 20063610, 화합물

HRID 359641노트

반응식

HRID 359641 반응식
[NH2:1][C:2]1[C:7]([O:8][CH3:9])=[C:6]([N+:10]([O-:12])=[O:11])[C:5]([O:13][CH3:14])=[CH:4][C:3]=1[O:15][CH3:16].[CH:17](O)=[O:18]>O>[CH:17]([NH:1][C:2]1[C:7]([O:8][CH3:9])=[C:6]([N+:10]([O-:12])=[O:11])[C:5]([O:13][CH3:14])=[CH:4][C:3]=1[O:15][CH3:16])=[O:18]

참가 물질

4

반응물 2

HCID 284Formic AcidHCID 23009735HCID 23009735, 화합물

생성물 1

HCID 20063610HCID 20063610, 화합물

시약·촉매·용매 1

HCID 962Water용매

실험 절차

A mixture comprising 0.11 mole (26.6 g) of 2-amino-4-nitro-1,3,5-trimethoxybenzene and 55 ml of formic acid are refluxed during three hours. The reaction mixture is cooled and diluted with iced water. The expected product precipitates and is separated by filtration. After drying it is recrystallized from ethanol. It melts at 98° C.

후처리

  1. temperatureThe reaction mixture is cooled
  2. customThe expected product precipitates
  3. customis separated by filtration
  4. customAfter drying it
  5. customis recrystallized from ethanol

출처 및 근거

ORD 기록
ord-29fa187fbf714e038a1767d6e11d47d9
출처 데이터셋
uspto-grants-1991_03
특허 번호
US05002585

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