1,2-Diallyloxybenzene → 1,2-Diallyloxybenzene

HRID 361129노트

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HRID 361129 반응식
C=CCOc1ccccc1OCC=C>CCOC(C)=O.O=C1CC[C@H]2CO[C@@H]1O2>C=CCc1ccc(CC=C)c(O)c1O.C=CCc1ccc(O)c(O)c1CC=C

참가 물질

7

반응물 1

HCID 778941,2-Diallyloxybenzene

생성물 3

HCID 778941,2-Diallyloxybenzene수율 56.382%HCID 131583253,4-Diallylbenzene-1,2-diol수율 12.608%HCID 132276783,6-Bis(prop-2-enyl)benzene-1,2-diol수율 20.772%

시약·촉매·용매 3

HCID 8857Ethyl Acetate용매HCID 10975499(1S,5R)-6,8-Dioxabicyclo[3.2.1]octan-4-one용매HCID 7500Ethylbenzene내부 표준

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온도
200 °C
기타
Reaction carried out in transient flow with ramps to vary the binary solvent composition, temperature and residence time. This reaction represents a single HPLC measurement sampled from within a transient flow ramp. Conditions are an estimate of what the reaction sample was exposed to prior to analysis.

후처리

  1. temperatureThe solution flowed through a customized cooling system made from an aluminum block and a Peltier assembly to quench the reaction.
  2. aliquotA Vici 4 port 2 position sampling valve sampled small aliquots (500 nL) into the HPLC for online analysis measurements of the reaction.

출처 및 근거

ORD 기록
ord-cd52dec94fdf4fac8458341818ee0ce5
출처 데이터셋
Transient flow exploration of the effect of temperature, residence time and binary solvent ratios on a uni-molecular allyl substituted catechol reaction.
원본 링크
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