Dimethylformamide → N-butyl-N-(2-methylprop-2-eneyl)aniline
반응식
[CH2:1]([NH:5][C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1)[CH2:2][CH2:3][CH3:4].C(=O)([O-])[O-].[K+].[K+].Cl[CH2:19][C:20]([CH3:22])=[CH2:21].CN(C=O)C>C1(C)C=CC=CC=1>[CH2:1]([N:5]([CH2:21][C:20]([CH3:22])=[CH2:19])[C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1)[CH2:2][CH2:3][CH3:4]참가 물질
6
반응 조건
- 온도
- 90 °C
실험 절차
A mixture of N-butylaniline (12.35 parts), anhydrous potassium carbonate (17.1 parts), 3-chloro-2-methylpropene (11.24 parts) and DMF (20 parts) was stirred at 90° C. for 8 hours. The cooled mixture was poured into toluene, washed with water (×2), 1N hydrochloric acid (30 parts) and water (×2). The dried organic phase was evaporated to leave N-butyl-N-(2-methylprop-2-eneyl)aniline (14.3 parts).
후처리
- washwashed with water (×2), 1N hydrochloric acid (30 parts) and water (×2)
- customThe dried organic phase was evaporated
출처 및 근거
- ORD 기록
- ord-6202f9c73b3f43119b22e8e6eec14055
- 출처 데이터셋
- uspto-grants-1999_02
- 특허 번호
- US05865857
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