참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | 1-Bromopentane | HCID 8057 | — |
| 반응물 | Potassium Carbonate | HCID 11430 | — |
| 반응물 | 3-Bromophenol | HCID 11563 | — |
| 용매 | Dimethylformamide | HCID 6228 | — |
| 생성물 | 3-Bromophenol | HCID 11563 | — |
| 생성물 | Pentyl ether | HCID 12743 | — |
반응 단계
To a solution of 5.0 gm of 3-Bromophenol in 60 mls of dimethylformamide is added 6.0 gm of potassium carbonate followed by 4.3 ml of 1-bromopentane. This mixture is heated to 60° C. for 6 hours and then cooled to room temperature and filtered. The filtrate is diluted with ether and washed with water and brine. After drying over magnesium sulfate and concentrating, the crude oil obtained is chromatographed over silica gel, and eluted with 3:2 hexane:ether to yield 3-bromo-phenol, n-pentyl ether as a clear oil.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US05412137 |
|---|
| 출처 데이터셋 | uspto-grants-1995_05 |
|---|
| ORD ID | ord-de9358811e8a412f9a03ad3430e27453 |
|---|
| 출처 메모 | uspto-grants-1995_05 |
|---|
