Tetraethylenepentamine → dodecylphenol TEPA

HRID 362763

반응식

HRID 362763 반응식
[CH2:1]([C:13]1[CH:18]=[CH:17][CH:16]=[CH:15][C:14]=1[OH:19])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12].O1CCCOO1.[NH2:26][CH2:27][CH2:28][NH:29][CH2:30][CH2:31][NH:32][CH2:33][CH2:34][NH:35][CH2:36][CH2:37][NH2:38]>O>[CH2:1]([C:13]1[CH:18]=[CH:17][CH:16]=[CH:15][C:14]=1[OH:19])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12].[NH2:38][CH2:37][CH2:36][NH:35][CH2:34][CH2:33][NH:32][CH2:31][CH2:30][NH:29][CH2:28][CH2:27][NH2:26]

참가 물질

5

반응물 3

HCID 8197TetraethylenepentamineHCID 1711442-DodecylphenolHCID 19593658CID 19593658

생성물 1

HCID 131721124dodecylphenol TEPA

시약·촉매·용매 1

HCID 962Water용매3회

실험 절차

To a 2 liter 4-necked reaction flask equipped with a stirrer, Dean Stark trap, condenser and nitrogen sparger were charged dodecylphenol (524 g, 2.0 m), trioxane (60 g, 0.66 m) and tetraethylene pentamine (TEPA) (189 g, 1.0 m). The temperature was raised slowly to 110° C. at which time water evolution began. After 8 hours the temperature had risen to 115° C. and water evolution ceased (42 cc's of water were collected). The mixture was cooled and filtered to yield 730g of a dodecylphenol-TEPA product containing 9.1% nitrogen.

후처리

  1. customTo a 2 liter 4-necked reaction flask equipped with a stirrer
  2. customwere collected)
  3. temperatureThe mixture was cooled
  4. filtrationfiltered

출처 및 근거

ORD 기록
ord-4f58afb3223547e1a8436c589d685f8c
출처 데이터셋
uspto-grants-1999_02
특허 번호
US05872082

연결된 노트

불러오는 중…