Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Phosphorus tribromide → 1-(Benzyloxy)-4-(bromomethyl)benzene
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Phosphorus tribromide | HCID 24614 | — |
| 반응물 | (4-(Benzyloxy)phenyl)methanol | HCID 70043 | — |
| 용매 | Diethyl Ether | HCID 3283 | — |
| 생성물 | 1-(Benzyloxy)-4-(bromomethyl)benzene | HCID 10492756 | — |
반응 단계
To a cold suspension of 4-benzyloxybenzyl alcohol 9-1 (21.4 g, 0.10 mol) in ether (250 ml) was added phosphorus tribromide (10.8 g, 40 mmol) as in Example 7. Recovered 27.2 g of white solid which was recrystallized from hexane (200 ml). Obtained pure bromide 9-2.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05872138 |
| 출처 데이터셋 | uspto-grants-1999_02 |
| ORD ID | ord-e5a47c0fc77a480b9fd05105ab39cd9c |
| 출처 메모 | uspto-grants-1999_02 |