참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | 1-Chloro-4-(trifluoromethyl)benzene | HCID 7394 | — |
| 반응물 | Allyl Alcohol | HCID 7858 | — |
| 반응물 | Potassium Hydroxide | HCID 14797 | — |
| 용매 | Sulfolane | HCID 31347 | — |
| 생성물 | Propenyl 4-trifluoromethylphenyl ether | HCID 86740963 | 68% |
반응 단계
174 g of allyl alcohol was added to a mixture of 298 g of 85% flake potassium hydroxide and 750 ml of sulpholane under nitrogen, and the mixture was heated to 125°-135° C. 272 g of 4-chlorobenzotrifluoride was added over 20 minutes at this temperature. After 2 hours, the reaction mixture was cooled to 30° C., and distillation from the solvent gave 207 g of propenyl 4-trifluoromethylphenyl ether b.p.: 84°-88° C. at 15 Torr.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US04607128 |
|---|
| 출처 데이터셋 | uspto-grants-1986_08 |
|---|
| ORD ID | ord-be72b45bf65b4194a2433b74d140fc6c |
|---|
| 출처 메모 | uspto-grants-1986_08 |
|---|
