참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Hydroquinone | HCID 785 | — |
| 반응물 | 1,3-Butadiene | HCID 7845 | — |
| 반응물 | 1,2-Dimethoxy-4-(2-nitrovinyl)benzene | HCID 709688 | — |
| 용매 | Toluene | HCID 1140 | — |
| 생성물 | (+/-)-trans-1,2-DI methoxy-4-(2-nitrocyclohex-4-enyl)benzene | HCID 53874256 | 76.3% |
반응 단계
50.0 g of 3,4-dimethoxy-ω-nitrostyrene and 1.0 g (9.1 mmol) of hydroquinone are suspended in 200 ml of abs. toluene and treated at -70° C. with 55.0 g (1.02 mol) of liquid 1,3-butadiene. The mixture is stirred at 160° C. for 6 days in an autoclave and then cooled. Some of the solvent is distilled off in vacuo, and the resulting precipitate is filtered off with suction and recrystallized in ethanol. M.p.: 113.5-115.5° C.; yield 76.3% of theory.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US06127378 |
|---|
| 출처 데이터셋 | uspto-grants-2000_10 |
|---|
| ORD ID | ord-80b19b11bbcd4405bbfa02d15544a6ef |
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| 출처 메모 | uspto-grants-2000_10 |
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