Stigmastan-3-ol → (-)-beta-Sitosterol

HRID 366281노트

반응식

HRID 366281 반응식
[CH3:1][CH2:2][CH:3]([CH:28]([CH3:30])[CH3:29])[CH2:4][CH2:5][CH:6]([CH:8]1[C:12]2([CH3:27])[CH2:13][CH2:14][CH:15]3[C:20]4([CH3:26])[CH2:21][CH2:22][CH:23]([OH:25])[CH2:24][CH:19]4[CH2:18][CH2:17][CH:16]3[CH:11]2[CH2:10][CH2:9]1)[CH3:7].CC[C@@H](C(C)C)CC[C@H]([C@@H]1[C@@]2(C)CC[C@@H]3[C@@]4(C)CC[C@H](O)C[C@@H]4CC[C@H]3[C@@H]2CC1)C>>[CH3:1][CH2:2][C@@H:3]([CH:28]([CH3:29])[CH3:30])[CH2:4][CH2:5][C@H:6]([C@@H:8]1[C@@:12]2([CH3:27])[CH2:13][CH2:14][C@@H:15]3[C@@:20]4([CH3:26])[CH2:21][CH2:22][C@H:23]([OH:25])[CH2:24][C:19]4=[CH:18][CH2:17][C@H:16]3[C@@H:11]2[CH2:10][CH2:9]1)[CH3:7]

참가 물질

3

반응물 2

HCID 6743Stigmastan-3-olHCID 241572Sitostanol

생성물 1

HCID 222284(-)-beta-Sitosterol

실험 절차

Pure sitostanol or stigmastanol is a commercial product obtained by catalytic hydrogenation of sitosterol. Its synthesis from beta-sitosterol was described in 1937: Bernstein, Wallis, J. Org. Chem Soc., 2, 341.

출처 및 근거

ORD 기록
ord-7def4175f2804e9789ddea2347181204
출처 데이터셋
uspto-grants-2000_10
특허 번호
US06129924

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