Methyl 2-(2-methoxy-2-oxoethyl)benzoate → 5-Nitrophenanthrene-1,10-dicarboxylic Anhydride

반응식

[C:1]([O:14]C)(=[O:13])[CH2:2][C:3]1[C:4](=[CH:9][CH:10]=[CH:11][CH:12]=1)[C:5]([O:7]C)=O.Br[C:17]1[C:24]([N+:25]([O-:27])=[O:26])=[CH:23][CH:22]=[CH:21][C:18]=1[CH:19]=O>>[N+:25]([C:24]1[CH:23]=[CH:22][CH:21]=[C:18]2[C:17]=1[C:12]1[CH:11]=[CH:10][CH:9]=[C:4]3[C:5](=[O:7])[O:14][C:1](=[O:13])[C:2](=[CH:19]2)[C:3]=13)([O-:27])=[O:26]

참가 물질

반응물 2

HCID 253507Methyl 2-(2-methoxy-2-oxoethyl)benzoate

HCID 131624082-Bromo-3-nitrobenzaldehyde

생성물 1

HCID 105897825-Nitrophenanthrene-1,10-dicarboxylic Anhydride

실험 절차

As described in example 50, the following compounds were prepared from dimethyl homophthalate and 2-bromo-3-nitrobenzaldehyde (Rahman, L. K. A.; Scrowston, R. M. J. Chem. Soc. Perkin Trans. 1 1984, 385):

출처 및 근거

ORD 기록: ord-896aa61bf3ac448a94a6b7fa5f540017
출처 데이터셋: uspto-grants-1995_05
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US05416089

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