참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Allyl chloride | HCID 7850 | — |
| 반응물 | Sodium hydride | HCID 24758 | — |
| 반응물 | N-(1,1-dimethoxyprop-2-yl)urethane | HCID 15069987 | — |
| 반응물 | HCID 178418361 | HCID 178418361 | — |
| 용매 | Toluene | HCID 1140 | — |
| 생성물 | N-Allyl-N-(1,1-dimethoxyprop-2-yl)-urethane | HCID 15069988 | — |
반응 단계
131 g (0.686 mol) of N-(1,1-dimethoxyprop-2-yl)urethane are added dropwise to 25 g of sodium hydride (80% strength) in 700 ml of absolute toluene at 90° C. When the evolution of hydrogen has ended, 61.2 g (0.8 mol) of allyl chloride are added dropwise at 90° C and the mixture is stirred overnight at 90° C. The sodium chloride which has precipitated out is dissolved with water, the organic phase is separated off, dried over K2CO3 and concentrated and the residue is distilled.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| 특허 번호 | US05416096 |
|---|
| 출처 데이터셋 | uspto-grants-1995_05 |
|---|
| ORD ID | ord-b43a0c6fcedb452497400e46b1e3cb3d |
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| 출처 메모 | uspto-grants-1995_05 |
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