Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
2,6-Di-t-butyl-p-benzoquinone → 2,6-Di-tertiary-butyl-4-(4'-cyanomethylphenylimino)-2,5-cyclohexadiene-1-one
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 2,6-Di-t-butyl-p-benzoquinone | HCID 12867 | — |
| 반응물 | 4-Aminophenylacetonitrile | HCID 77000 | — |
| 생성물 | 2,6-Di-tertiary-butyl-4-(4'-cyanomethylphenylimino)-2,5-cyclohexadiene-1-one | HCID 22401559 | — |
반응 단계
Using the method of Example 1, 4-aminobenzylcyanide was reacted with 2,6-di-tertiary-butyl-p-benzoquinone to give 2,6-di-tertiary-butyl-4-(4'-cyanomethylphenylimino)-2,5-cyclohexadiene-1-one, m.p. 126.5°-127.5° C. Following the reduction method of Example 1, Step B, the corresponding anilino phenylacetonitrile, m.p. 146°-147° C., was obtained. This was converted to 5-[4-(3,5-di-t-butyl-4-hydroxyanilino)benzyl]tetrazole, m.p. 212°-214° C. (dec), following the method of Example 30, but carried out at 110° C. for 48 hours.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05416113 |
| 출처 데이터셋 | uspto-grants-1995_05 |
| ORD ID | ord-0667c16ef61a44ee8420eb89fd26b0da |
| 출처 메모 | uspto-grants-1995_05 |