Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Sodium Cyanide → 4-Chlorobenzonitrile
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Sodium Cyanide | HCID 8929 | — |
| 반응물 | 4-Chlorobenzene-1-diazonium; tetrafluoroboranuide | HCID 11085506 | — |
| 용매 | Water | HCID 962 | — |
| 생성물 | 4-Chlorobenzonitrile | HCID 12163 | 75% |
반응 단계
Sodium cyanide (2.94 g; 0.06 mol) was added to water and stirred. Cuprous cyanide (2.7 g; 0.03 mol) was added to the mixture stirred until it became homogeneous. 4-chlorobenzenediazonium tetrafluoroborate (5.66 g; 0.025 mol) in water (10 ml) was added to one portion. The mixture was allowed to react at room temperature. The mixture was extracted by ethyl acetate and the extract analysed by means of gas chromatography which indicated that 4-chlorobenzonitrile had been formed in 75% yield.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05416235 |
| 출처 데이터셋 | uspto-grants-1995_05 |
| ORD ID | ord-e6b27fd42fc5429c84905e1158cb162b |
| 출처 메모 | uspto-grants-1995_05 |