Isophorone → Acetate

반응식

O=[C:2]1[CH2:9][C:6]([CH3:8])([CH3:7])[CH2:5][C:4]([CH3:10])=[CH:3]1.[C:11]([O:14][CH:15]=[CH2:16])(=[O:13])[CH3:12]>>[CH3:7][C:6]1([CH3:9])[CH2:5][C:4]2([CH3:10])[CH:14]([CH2:2][CH2:3]2)[C:15](=[O:16])[CH2:8]1.[C:11]([O-:14])(=[O:13])[CH3:12]

참가 물질

반응물 2

HCID 6544Isophorone

HCID 7904Vinyl Acetate

생성물 2

HCID 175Acetate

HCID 227655154,4,6-Trimethylbicyclo[4.2.0]octan-2-one

실험 절차

The photochemical reaction system of this invention is illustrated by another dual irradiation in which the inner flask reaction is the same as in Example 1, but in which the photochemical reaction in the outer flask consists in reacting isophorone with vinyl acetate to yield 4,4,6-trimethyl bicyclo[4.2.0]octane-2-one (7 or 8) acetate: ##STR3##

후처리

customThe photochemical reaction system of this invention is illustrated by another dual irradiation in which
customthe inner flask reaction
customin which the photochemical reaction in the outer flask

출처 및 근거

ORD 기록: ord-f7fda218d56f47c2abc4519a6d931870
출처 데이터셋: uspto-grants-1978_05
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US04087342

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