HCID 20354850, 화합물 → HCID 20354859, 화합물

HRID 372123노트

반응식

HRID 372123 반응식
[C:1]([O:4][CH:5]([CH2:15][CH2:16][CH2:17][CH2:18][CH3:19])[CH2:6][CH2:7][C:8]12O[CH:12]1[CH2:11][CH2:10][C:9]2=[O:14])(=[O:3])[CH3:2]>C(O)(=O)C>[C:1]([O:4][CH:10]1[C:9](=[O:14])[C:8]([CH2:7][CH2:6][CH:5]([O:4][C:1](=[O:3])[CH3:2])[CH2:15][CH2:16][CH2:17][CH2:18][CH3:19])=[CH:12][CH2:11]1)(=[O:3])[CH3:2]

참가 물질

3

반응물 1

HCID 20354850HCID 20354850, 화합물

생성물 1

HCID 20354859HCID 20354859, 화합물수율 159.4%

시약·촉매·용매 1

HCID 176Acetic Acid용매

실험 절차

A solution of 2-(3-acetoxyoctyl)-2,3-epoxycyclopentanone (26.8 g.) [prepared as described in (g) above] in glacial acetic acid (500 ml.) was heated at reflux for 12 hours. The excess acetic acid was then removed in vacuo and the residue distilled under reduced pressure to give 5-acetoxy-2-(3-acetoxyoctyl)cyclopent-2-enone (24.7 g.), b.p. 164°-175° C./0.2 mm.Hg.

후처리

  1. temperatureat reflux for 12 hours
  2. customThe excess acetic acid was then removed in vacuo
  3. distillationthe residue distilled under reduced pressure

출처 및 근거

ORD 기록
ord-e62f4f1644c7484e8921f7d286bf7b23
출처 데이터셋
uspto-grants-1978_05
특허 번호
US04088821

반응 노트

불러오는 중…