Magnesium Hydroxide → Magnesium tartrate

HRID 372663

반응식

[C@@H:1]1([C:7]([OH:9])=[O:8])[O:3][C@@H:2]1[C:4]([OH:6])=[O:5].[OH-:10].[Mg+2:11].[OH-]>>[C:7]([C@@H:1]([C@H:2]([C:4]([O-:6])=[O:5])[OH:10])[OH:3])([O-:9])=[O:8].[Mg+2:11]

참가 물질

반응물 2

HCID 73981Magnesium Hydroxide

HCID 2734802cis-Epoxysuccinate

생성물 1

HCID 71586781Magnesium tartrate수율 91%

반응 조건

온도: 35 °C

실험 절차

In 100 ml of an aqueous solution containing 1.0 g of cis-epoxysuccinic acid and 0.44 g of magnesium hydroxide and adjusted to pH value of 8.0, a 0.5 g portion of clean microbic cells of Acetobacter curtus No. 4 (FERM-P No. 2879) obtained by following the procedure of Example 3 was added and shaken at 35° C for 5 hours. In the reaction mixture, there was formed magnesium L(+)-tartrate. The amount of the salt thus produced was 1.19 g and the yield was 91 percent. By treating this product with a column packed with Amberlite IR 120 (H+ type cation-exchange resin) similarly to Example 3, there was obtained L(+)-tartaric acid. This L(+)-tartaric acid was found to have an optical purity of 100 percent.

후처리

custom4 (FERM-P No. 2879) obtained
additionwas added

출처 및 근거

ORD 기록: ord-3b47aaeac51f415b948c6b0173645e45
출처 데이터셋: uspto-grants-1978_05
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US04092220

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