Allylamine → 2,2,4-Trimethyl-1-allyl-1-aza-2-silacyclopentane

HRID 373344

반응식

HRID 373344 반응식
Cl[Si:2]([CH3:9])([CH3:8])[CH2:3][CH:4]([CH3:7])[CH2:5]Cl.[CH2:10]([NH2:13])[CH:11]=[CH2:12]>>[CH3:8][Si:2]1([CH3:9])[CH2:3][CH:4]([CH3:7])[CH2:5][N:13]1[CH2:10][CH:11]=[CH2:12]

참가 물질

3

반응물 2

HCID 7853AllylamineHCID 86665Chloro(3-chloro-2-methylpropyl)dimethylsilane

생성물 1

HCID 191071842,2,4-Trimethyl-1-allyl-1-aza-2-silacyclopentane

실험 절차

1,1,4-Trimethyl-2-allyl-2-aza-silacyclopentane was prepared. Chlorodimethyl(3-chloro-2-methylpropyl)silane (100 g, 0.54 mol) was slowly added to 211.73 g (3.71 mol, 6.87 eq) of undistilled allyl amine resulting in an exothermic reaction. This reaction mixture was stirred at room temperature for 15 hours, heated to reflux at atmospheric pressure for 72 hours, and heated to 120° C. under about 50 psig pressure for 16 hours. The following GC-MS ratios shown in Table I exemplified the reactions progression and the spectra observed were as shown.

후처리

  1. temperatureheated
  2. temperatureto reflux at atmospheric pressure for 72 hours
  3. temperatureheated to 120° C. under about 50 psig pressure for 16 hours

출처 및 근거

ORD 기록
ord-898fd8da6c3440ab966d6e36af3519da
출처 데이터셋
uspto-grants-1992_11
특허 번호
US05162560

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