Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
3-Iodoaniline → 2,2'-Dithiobis[N-(3-iodophenyl)benzamide]
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 3-Iodoaniline | HCID 12271 | — |
| 반응물 | 2,2'-Dithiodibenzoyl chloride | HCID 88164 | — |
| 용매 | Pyridine | HCID 1049 | — |
| 용매 | Dichloromethane | HCID 6344 | — |
| 생성물 | 2,2'-Dithiobis[N-(3-iodophenyl)benzamide] | HCID 18935309 | 7.3% |
반응 단계
This compound was prepared according to the general method of Example 77 using 2,2'-dithiobisbenzoyl chloride (3.00 g, 8.74 mmol) in 75 mL of dichloromethane and 3-iodoaniline (3.82 g, 17.5 mmol) in 17 mL of pyridine. The crude product was triturated with hot ethanol, filtered, and recrystallized first from water-DMF, then from ethyl acetate-ether to yield 0.45 g of the title compound, mp 184°-186° C. (dec.).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05734081 |
| 출처 데이터셋 | uspto-grants-1998_03 |
| ORD ID | ord-820622bd6d264f8c8a3784a27744ca1b |
| 출처 메모 | uspto-grants-1998_03 |