1,1,1,3,3,3-Hexafluoro-2-propyl methacrylate → Alpha-Methylstyrene

HRID 374557

반응식

HRID 374557 반응식
C(OC(C(F)(F)F)C(F)(F)F)(=O)C(C)=C.O=C=NC1CC(C)(C)CC(C)(CN=C=O)C1.[C:32]([C:35]1[CH:36]=[C:37]([CH:44]=[CH:45][CH:46]=1)C(N=C=O)(C)C)([CH3:34])=[CH2:33]>>[CH3:34][C:32]([C:35]1[CH:36]=[CH:37][CH:44]=[CH:45][CH:46]=1)=[CH2:33]

참가 물질

4

반응물 3

HCID 764691,1,1,3,3,3-Hexafluoro-2-propyl methacrylateHCID 169132Isophorone diisocyanateHCID 6041521-(1-Isocyanato-1-methylethyl)-3-(1-methylethenyl)benzene

생성물 1

HCID 7407Alpha-Methylstyrene

실험 절차

9.045 g (5.53 m equiv. amine) of an α,ω-di-propylamino-poly-(dimethyl siloxane) of MW 1636 (Shin Etsu Corp. No. X-22-161A) are placed in a 1 oz. jar; 4.56 g of hexafluoroisopropyl methacrylate (F6MA) are added and the mixture is stirred and cooled in an ice-water bath. 0.21 g (0.9546 m moles) of isophorone diisocyanate (IPDI) are added and the mixture is stirred for 2 hours at room temperature until all isocycanate has disappeared (by IR). Then 1.85 g (9.22 m moles) m-isopropenyl-α,α-dimethylbenzyl isocyanate (TMI) are added and the mixture is stirred for 2 more hours to yield a clear viscous liquid of a 70.90% solution of α-methyl styrene capped, chain extended poly(dimethyl siloxane) of MW 2426 (calculated) in F6MA.

후처리

  1. temperaturecooled in an ice-water bath
  2. stirringthe mixture is stirred for 2 hours at room temperature until all isocycanate
  3. stirringthe mixture is stirred for 2 more hours

출처 및 근거

ORD 기록
ord-211bce0f83a84d9ca3ee5ed86965c952
출처 데이터셋
uspto-grants-1996_01
특허 번호
US05480946

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