Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Pyrrole → 21H,22H-Porphine
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Pyrrole | HCID 8027 | — |
| 반응물 | Pentafluorobenzaldehyde | HCID 69558 | — |
| 반응물 | Tri(pentafluorophenyl)porphyrin | HCID 87642297 | — |
| 생성물 | 21H,22H-Porphine | HCID 137705241 | — |
반응 단계
Compound C is subjected to a second Lindsey-type tri(pentafluorophenyl)porphyrin-ring construction with pentafluorobenzaldehyde and pyrrole, to give the Gable porphyrin, orthodi [mesotri(pentafluorophenyl)porphin]-benzene. In this step, Compound C is reacted again with pyrrole and pentafluorobenzaldehyde in a 1,4,3 molar ratio with BF3 0Et2 catalyst to give the desired ##STR5##
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05480986 |
| 출처 데이터셋 | uspto-grants-1996_01 |
| ORD ID | ord-69ca33a75c82441e9f07fe35dcfc1ae8 |
| 출처 메모 | uspto-grants-1996_01 |