Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
1-Hexene → Allylhexyldichlorosilane
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 1-Hexene | HCID 11597 | — |
| 반응물 | Dichloro(prop-2-enyl)silane | HCID 77536 | — |
| 촉매 | Chloroplatinic acid | HCID 61859 | — |
| 용매 | Isopropanol | HCID 3776 | — |
| 생성물 | Allylhexyldichlorosilane | HCID 11218382 | 79,283.797% |
반응 단계
Using the same apparatus and procedure described in EXAMPLE 1, 59.7 g (0.71 mol) of 1-hexene and 80 μl of 1% chloroplatinic acid in isopropanol were added to the flask. Through the dropping funnel was added dropwise 10 g (0.07 mmol) of allyldichlorosilane for 30 rain while refluxing. After confirming by gas chromatography to complete the reaction, vacuum distillation (48°-50° C./0.5 torr) gave 12.5 g (79.3%) of 4,4-dichloro-4-sila-1 -decene.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05420323 |
| 출처 데이터셋 | uspto-grants-1995_05 |
| ORD ID | ord-5969ae89b2384cd0b55903e6f6ceefcb |
| 출처 메모 | uspto-grants-1995_05 |