Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
4-Vinyl-1-cyclohexene → 6-(3-Hexenyl)-4,4-dichloro-4-sila-1-hexene
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 4-Vinyl-1-cyclohexene | HCID 7499 | — |
| 반응물 | Dichloro(prop-2-enyl)silane | HCID 77536 | — |
| 촉매 | Chloroplatinic acid | HCID 61859 | — |
| 용매 | Isopropanol | HCID 3776 | — |
| 생성물 | 6-(3-Hexenyl)-4,4-dichloro-4-sila-1-hexene | HCID 57089004 | 76,753.602% |
반응 단계
Using the same apparatus and procedure described in EXAMPLE 1, 37.8 g (0.35 mol) of 4-vinylcyclohexene and 60 μl of 1% chloroplatinic acid in isopropanol were added to the flask. Through the dropping funnel was added dropwise 10.0 g (0.07 mmol) of allyldichlorosilane for 30 min at 80° C. and the solution was further reacted for 3 hrs to complete the reaction. Vacuum distillation (70-73° C./0.5 torr) of the product mixture gave 13.5 g (78%) of 6-(3-hexenyl)-4,4-dichloro-4-sila-1-hexene.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05420323 |
| 출처 데이터셋 | uspto-grants-1995_05 |
| ORD ID | ord-a6e6ebd445904251982b712987aa6c82 |
| 출처 메모 | uspto-grants-1995_05 |