Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Allyl chloride → 7-Chloro-4,4-dimethoxy-4-sila-1-heptene
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Allyl chloride | HCID 7850 | — |
| 반응물 | Silane, dimethoxy-2-propenyl- | HCID 57370758 | — |
| 촉매 | Chloroplatinic acid | HCID 61859 | — |
| 생성물 | 7-Chloro-4,4-dimethoxy-4-sila-1-heptene | HCID 57172000 | 76,643.797% |
반응 단계
Using the same apparatus and procedure described in EXAMPLE 1, 7.7 g (0.1 mol) of allylchloride and 60 μl of 1% chloroplatinic acid catalyst were added to the flask. Through the dropping funnel was added dropwise 6.6 g (0.05 mmol) of allyldimethoxysilane for 30 min. while refluxing. After confirming by gas chromatography to complete the reaction, the product was fractionally distilled under vacuum (59°-62° C./0.5 torr) to give 8.0 g (81%) of 7-chloro-4,4-dimethoxy-4-sila-1-heptene.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05420323 |
| 출처 데이터셋 | uspto-grants-1995_05 |
| ORD ID | ord-e14f8e46d9d04b6cb3d23cd8636f5d42 |
| 출처 메모 | uspto-grants-1995_05 |