Water → Stannane, chlorotricyclohexyl-

HRID 376824

반응식

HRID 376824 반응식
[CH:1]1([Sn:7](C2CCCCC2)([CH:14]2[CH2:19][CH2:18][CH2:17][CH2:16][CH2:15]2)[CH:8]2[CH2:13][CH2:12][CH2:11][CH2:10][CH2:9]2)[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1.C1(C)C=CC=CC=1.[Sn](Cl)(Cl)(Cl)[Cl:34].O>CCCCCC>[CH:1]1([Sn:7]([Cl:34])([CH:14]2[CH2:19][CH2:18][CH2:17][CH2:16][CH2:15]2)[CH:8]2[CH2:13][CH2:12][CH2:11][CH2:10][CH2:9]2)[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1

참가 물질

6

반응물 4

HCID 962WaterHCID 1140TolueneHCID 24287Tin tetrachlorideHCID 74056Tetracyclohexylstannane

생성물 1

HCID 76539Stannane, chlorotricyclohexyl-수율 79.4%

시약·촉매·용매 1

HCID 8058Hexane용매

반응 조건

온도
0 °C

실험 절차

55.1 g of tetracyclohexyltin (122 mmol) and 50 ml of toluene were mixed together in a 200 ml eggplant type flask, and containing a stirrer. Then, 18.1 ml of tin tetrachloride (155 mmol) was added, and the mixture was refluxed for 3 hours. Upon completion of the reaction, the mixture was cooled to 0° C., and 30 ml of water and 50 ml of hexane were added. After the hexane layer was separated, the solid precipitate, which had been precipitated by removing the solvent under reduced pressure, was washed with 20 ml of acetonitrile, and dried under a vacuum, to yield 39.1 g of the final product (yield=59.5%).

후처리

  1. additioncontaining a stirrer
  2. temperaturethe mixture was refluxed for 3 hours
  3. customUpon completion of the reaction
  4. customAfter the hexane layer was separated
  5. customthe solid precipitate, which had been precipitated
  6. customby removing the solvent under reduced pressure
  7. washwas washed with 20 ml of acetonitrile
  8. customdried under a vacuum

출처 및 근거

ORD 기록
ord-6ac91b2795954443b6184e944ddc951b
출처 데이터셋
uspto-grants-2000_02
특허 번호
US06022822

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