Thionyl Chloride → 2,4-Dichloro-3-(1'-methoxyimino-1'-(methoxy)methyl)benzoyl chloride

HRID 377548노트

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HRID 377548 반응식
[Cl:1][C:2]1[C:10]([C:11](=[N:14][O:15][CH3:16])[O:12][CH3:13])=[C:9]([Cl:17])[CH:8]=[CH:7][C:3]=1[C:4](O)=[O:5].S(Cl)([Cl:20])=O>C1(C)C=CC=CC=1>[Cl:1][C:2]1[C:10]([C:11](=[N:14][O:15][CH3:16])[O:12][CH3:13])=[C:9]([Cl:17])[CH:8]=[CH:7][C:3]=1[C:4]([Cl:20])=[O:5]

참가 물질

4

반응물 2

HCID 24386Thionyl ChlorideHCID 536841302,4-Dichloro-3-(1'-(methoxy)imino-1'-methoxymethyl)benzoic acid

생성물 1

HCID 537630032,4-Dichloro-3-(1'-methoxyimino-1'-(methoxy)methyl)benzoyl chloride수율 99.8%

시약·촉매·용매 1

HCID 1140Toluene용매

실험 절차

A solution of 2.10 g (0.0076 mol) of 2,4-dichloro-3-(1'-(methoxy)imino-1'-methoxymethyl)benzoic acid and 20.00 g of thionyl chloride in 50 ml of dry toluene was stirred for 2 hours at 80° C. After the solvent had been removed in vacuo, 2.25 g of 2,4-dichloro-3-(1'-methoxyimino-1'-(methoxy)methyl)benzoyl chloride were obtained.

후처리

  1. customAfter the solvent had been removed in vacuo

출처 및 근거

ORD 기록
ord-1b7309e5a5c84657acb3c50eb733269e
출처 데이터셋
uspto-grants-2000_02
특허 번호
US06028035

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