Nitrogen → Di-tert-butyl ether

HRID 378770

반응식

HRID 378770 반응식
[CH2:1]=[C:2]([CH3:4])[CH3:3].C(O)CCCCC.N#N.C([O:20][C:21]([CH3:24])([CH3:23])[CH3:22])CCCCC>>[C:2]([O:20][C:21]([CH3:24])([CH3:23])[CH3:22])([CH3:4])([CH3:3])[CH3:1]

참가 물질

5

반응물 4

HCID 947NitrogenHCID 81031-Hexanol2회HCID 8255IsobutyleneHCID 547839Hexyl t-butyl ether

생성물 1

HCID 22541Di-tert-butyl ether

실험 절차

300 mmoles of i-butene, 100 mmoles of 1-hexanol and 2.5 g of Ti-Si-catalyst powder are stirred in a 100 ml autoclave at a pressure of 40 bar N2 and a temperature of 150° C. over a period of 18 h, 62% of n-hexanol were converted into hexyl-t-butyl ether with a selectivity of 92%.

출처 및 근거

ORD 기록
ord-6a5710d67e814d708dc3e64c5f91b38a
출처 데이터셋
uspto-grants-2001_10
특허 번호
US06297180B1

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