1-Ethyl-2-(phenylmethyl)benzene → Anthracene

HRID 380163

반응식

HRID 380163 반응식
[C:1]1([CH:7]2[C:15]3[C:10](=[CH:11][CH:12]=[CH:13][CH:14]=3)[CH:9]=[CH:8]2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[CH2:16]([C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][C:19]=1[CH2:24][C:25]1[CH:30]=[CH:29][CH:28]=[CH:27][CH:26]=1)[CH3:17]>>[C:1]1([C:7]2[C:8]3[C:9](=[CH:10][CH:11]=[CH:12][CH:13]=3)[CH:16]=[CH:14][CH:15]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[CH3:17][C:16]1[C:18]2[C:19]([C:24]([CH3:1])=[C:25]3[C:30]=1[CH:29]=[CH:28][CH:27]=[CH:26]3)=[CH:20][CH:21]=[CH:22][CH:23]=2.[CH3:8][C:7]1[C:15]2[C:10]([CH:9]=[C:2]3[C:1]=1[CH:6]=[CH:5][CH:4]=[CH:3]3)=[CH:11][CH:12]=[CH:13][CH:14]=2.[CH:5]1[C:6]2[C:1](=[CH:7][C:15]3[C:10]([CH:16]=2)=[CH:11][CH:12]=[CH:13][CH:14]=3)[CH:2]=[CH:3][CH:4]=1

참가 물질

6

반응물 2

HCID 1198231-Ethyl-2-(phenylmethyl)benzeneHCID 5196741-Phenyl-1H-indene

생성물 4

HCID 8418AnthraceneHCID 117951-PhenylnaphthaleneHCID 130689-MethylanthraceneHCID 130769,10-Dimethylanthracene

실험 절차

1-Phenylindene and the like are prepared from (o-ethylphenyl)phenylmethane. 1-Phenylnaphthalene (boiling point: 324-325° C.), 9,10-dimethylanthracene (melting point: 182-184° C.), and 9-methylanthracene obtained by elimination of a methyl group of 9,10-dimethylanthracene, anthracene (melting point: 216-218° C., boiling point: 342° C.) and the like are prepared from 1-(o-ethylphenyl)-1-phenylethane.

출처 및 근거

ORD 기록
ord-b93d1d5a317e4bbdbd0b375b5fce75c4
출처 데이터셋
uspto-grants-2001_10
특허 번호
US06300534B1

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