Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Nitromethane → o-Bromo-nitrostyrene
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Nitromethane | HCID 6375 | — |
| 반응물 | Sodium Hydroxide | HCID 14798 | — |
| 반응물 | 2-Bromobenzaldehyde | HCID 81129 | — |
| 용매 | Methanol | HCID 887 | — |
| 용매 | Water | HCID 962 | — |
| 생성물 | o-Bromo-nitrostyrene | HCID 187792 | — |
반응 단계
To a solution of o-bromo-benzaldehyde (4 g, 21.6 mmol) and nitromethane (1.32 g, 21.6 mmol) in methanol (5 mL) was added NaOH (0.908 g, 22.7 nmol) in 1 mL of H2O. After 45 minutes, the precipitate was dissolved in 10 mL of H2O. The product precipitated out after the addition of 6N HCl. The product was recrystallized from ethanol; 0.312 g (6%).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US06300501B1 |
| 출처 데이터셋 | uspto-grants-2001_10 |
| ORD ID | ord-3a7147da77924b19a957e1149337a4ea |
| 출처 메모 | uspto-grants-2001_10 |