Methylhydroquinone → Durohydroquinone

HRID 380777

반응식

HRID 380777 반응식
[CH3:1]C1C=C(O)C=CC=1O.CC1C(C)=C(C=CC=1O)O.[CH3:20][C:21]1[C:22]([OH:30])=[C:23]([CH3:29])[C:24]([CH3:28])=[C:25]([CH:27]=1)[OH:26]>[Fe].CO>[CH3:20][C:21]1[C:22]([OH:30])=[C:23]([CH3:29])[C:24]([CH3:28])=[C:25]([OH:26])[C:27]=1[CH3:1]

참가 물질

6

반응물 3

HCID 7253Methylhydroquinone2회HCID 12785TrimethylhydroquinoneHCID 691002,3-Dimethylhydroquinone

생성물 1

HCID 136346Durohydroquinone

시약·촉매·용매 2

HCID 23925Iron촉매HCID 887Methanol용매

실험 절차

Into an autoclave (inner volume: 9 ml, made of SUS 316, equipped with a manometer) were charged 0.104 g of methylhydroquinone, 3.4078 g of methanol and 8.3 mg of iron powders (manufactured by Wako Pure Chemical Ind., Ltd.). The reaction was started by elevating the temperature up to 350° C. with sand bath. The pressure during the reaction was 20 MPa. After 2 hours, the autoclave was quickly cooled and the reaction solution was taken out from the autoclave when the temperature was cooled back to the room temperature. The measurement according to the process described above revealed that the conversion of methylhydroquinone was 16% by mole, the selectivity of dimethylhydroquinone was 82% by mole and the selectivity of trimethylhydroquinone was 3% by mole. No tetramethylhydroquinone was produced.

후처리

  1. customequipped with a manometer)
  2. customup to 350° C.
  3. temperaturethe autoclave was quickly cooled

출처 및 근거

ORD 기록
ord-af2687bb1220432cb1ed01fbda9f5006
출처 데이터셋
uspto-grants-2001_10
특허 번호
US06303801B1

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