trans-4-Bromo-beta-nitrostyrene → 1-Bromo-4-[(trans)-2-nitrocyclopropyl]benzene

HRID 38112

반응식

HRID 38112 반응식
C(O[C:9]1[CH:14]=[CH:13][C:12]([C@H:15]2[CH2:17][C@@H:16]2[N+:18]([O-:20])=[O:19])=[CH:11][CH:10]=1)C1C=CC=CC=1.[Br:21]C1C=CC(/C=C/[N+]([O-])=O)=CC=1>>[Br:21][C:9]1[CH:14]=[CH:13][C:12]([C@@H:15]2[CH2:17][C@H:16]2[N+:18]([O-:20])=[O:19])=[CH:11][CH:10]=1

참가 물질

3

반응물 2

HCID 688204trans-4-Bromo-beta-nitrostyreneHCID 666295831-(benzyloxy)-4-((1R,2S)-2-nitrocyclopropyl)benzene

생성물 1

HCID 670646391-Bromo-4-[(trans)-2-nitrocyclopropyl]benzene수율 27%

실험 절차

This compound was synthesized using the same methodology described in Intermediate A, using the commercially available 1-bromo-4-[(trans)-2-nitrovinyl]benzene as starting material. 27% yield

후처리

  1. customThis compound was synthesized

출처 및 근거

ORD 기록
ord-241cd0baadbf46bfade40801c399eb81
출처 데이터셋
uspto-grants-2013_09
특허 번호
US08524717B2

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