Glycerol → Hydroxymethyl-2-methyl-2-undecyl-1,3-dioxolane

HRID 381721

반응식

HRID 381721 반응식
[CH3:1][C:2](=[O:14])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH3:13].[OH:15][CH2:16][CH:17]([CH2:19]O)[OH:18]>C1(C)C=CC(S(O)(=O)=O)=CC=1.C1(C)C=CC=CC=1>[CH3:1][C:2]1([CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH3:13])[O:18][CH:17]([CH2:16][OH:15])[CH2:19][O:14]1

참가 물질

5

반응물 2

HCID 753GlycerolHCID 116222-Tridecanone

생성물 1

HCID 10265274Hydroxymethyl-2-methyl-2-undecyl-1,3-dioxolane

시약·촉매·용매 2

HCID 6101p-Toluenesulfonic acid촉매HCID 1140Toluene용매

실험 절차

A reactor equipped with a stirrer, reflux-condenser, thermometer and nitrogen gas inlet pipe was charged with 297 g of 2-tridecanone, 166 g of glycerol and a solvent amount of toluene, and following addition of p-toluenesulfonic acid as a catalyst, the dehydrative condensation reaction was carried out at the reflux temperature for 24 hours. The resulting crude product was washed with an aqueous solution of potassium carbonate and further with 3 portions of distilled water and finally purified by distillation under reduced pressure to provide 2-methyl-2-undecyl-4-hydroxymethyl-1,3-dioxolane.

후처리

  1. customA reactor equipped with a stirrer, reflux-condenser
  2. customthe dehydrative condensation reaction
  3. washThe resulting crude product was washed with an aqueous solution of potassium carbonate and further with 3 portions of distilled water
  4. distillationfinally purified by distillation under reduced pressure

출처 및 근거

ORD 기록
ord-214fdd25f1464e14aa3333cfe6c3fc5a
출처 데이터셋
uspto-grants-2001_10
특허 번호
US06307069B1

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