Toluene 2,4-Diisocyanate → Urethane acrylate

Into a reaction vessel equipped with a stirrer were charged 5.5 parts of tolylene diisocyanate, 42.0 parts of a ring-opening copolymer from tetrahydrofuran and 3-methyltetrahydrofuran, having a number average molecular weight of 2,000, and 0.01 part of 2,6-di-t-butyl-p-cresol, as a polymerization inhibitor. The mixture was cooled with ice to a temperature of below 10° C., while stirring. When the temperature was lower than 10° C., 0.04 part of dibutyltindilaurate was added and the mixture was stirred for 2 hours while controlling the temperature at 20-30° C. Then, after the addition of 2.2 parts of hydroxyethyl acrylate, the mixture was stirred for 4 hours at 50-60° C., until the amount of remaining isocyanate is 0.1% by weight or less. The Liquid urethane acrylate obtained in this manner is hereinafter referred to as UA-2.

1. customInto a reaction vessel equipped with a stirrer
2. temperatureThe mixture was cooled with ice to a temperature of below 10° C.
3. customwas lower than 10° C.
4. addition0.04 part of dibutyltindilaurate was added
5. stirringthe mixture was stirred for 2 hours
6. customat 20-30° C

ORD 기록

ord-b7ccaa906f244a06a79f4901ece83a92

출처 데이터셋

uspto-grants-2001_10

DOI

10.6084/m9.figshare.5104873.v1

특허 번호

US06309747B1