Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Iodine → Muconic Acid
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Iodine | HCID 807 | — |
| 반응물 | (2E,4Z)-2,4-Hexadienedioic acid | HCID 5280614 | — |
| 용매 | 1-Butanol | HCID 263 | — |
| 생성물 | Muconic Acid | HCID 5356793 | 76.2% |
반응 단계
cis,trans-Muconic acid (105 mg, 0.739 mmol) is dissolved in n-butanol (10 mL) at room temperature and a crystal of iodine (17 mg, 0.067 mmol) is added. The reaction mixture is allowed to stir at room temperature for 24 hours. The precipitate is filtered, washed with ice-cold acetonitrile and dried under reduced pressure to yield 80 mg of trans,trans-muconic acid, a 76 percent yield.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US08367858B2 |
| 출처 데이터셋 | uspto-grants-2013_02 |
| ORD ID | ord-71794a6dd7aa418083ef1ace501e0555 |
| 출처 메모 | uspto-grants-2013_02 |